Monday, April 25, 2011

6.1.2

6.1.2 Describe suitable experimental procedures for measuring rates of reactions



Experimental Method
Dependent and Independent variables
Diagram
Additional Notes
Change in volume of gas produced
Independent: time (sec)
Dependent: volume of gas (cm3)


Gas syringe best because inverted measuring cylinder or burette limited to gases with low solubility
Change in mass
 Independent: time(sec)
Dependent: mass of reactants(g)
 Unlikely to work well, because there might not be a significant decrease in mass for example hydrogen is too light
 Change in transmission of light: colorimery/
spectrophotometry
 Independent:
time(sec)
Dependent:
light intensity
 Only works with coloured compounds, as the concentration of compounds increases, more light is absorbed therefore less is transmitted
 Change in concentration measured using titration
 Independent:
time(sec)
Dependent:
concentration
(cm3)

 It cannot be done continuously thus samples must be taken from the reaction mixture. To avoid the mixture over reacting, a method called “quenching” can be used which provides a snap shot at the moment it is withdrawn.
Change in concentration measured using conductivity
Independent:
time(sec)
Dependent:
electrical conductivity

As reactants are converted into products, there’s a sharp decrease in the electricity conductivity as there’s a decrease in the concentration of ions
Non-continuous methods of detecting change during a reaction:”clock reactions”
Independent:
time(sec)
Dependent:
a magnesium ribbon disappearing or a cross view is no longer visible

It is more convenient to measure the time it takes for a reaction to reach a choosen fixed point

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